The phase diagram of ice: a quasi-harmonic study based on a flexible water model

The phase diagram of ice is studied by a quasi-harmonic approximation. The free energy of all experimentally known ice phases has been calculated with the flexible q-TIP4P/F model of water. The only exception is the high pressure ice X, in which the presence of symmetric O-H-O bonds prevents its modeling with this empirical interatomic potential. The simplicity of our approach allows us to study ice phases at state points of the T-P plane that have been omitted in previous simulations using free energy methods based on thermodynamic integration. The effect in the phase diagram of averaging the proton disorder that appears in several ice phases has been studied. It is found particularly relevant for ice III, at least for cell sizes typically used in phase coexistence simulations. New insight into the capability of the employed water model to describe the coexistence of ice phases is presented. We find that the H-ordered ices IX and XIV, as well as the H-disordered ice XII, are particularly stable for this water model. This fact disagrees with experimental data. The unexpected large stability of ice IX is a property related to the TIP4P-character of the water model. Only after omission of these three stable ice phases, the calculated phase diagram becomes in reasonable qualitative agreement to the experimental one in the T-P region corresponding to ice Ih, II, III, V, and VI. The calculation of the phase diagram in the quantum and classical limits shows that the most important quantum effect is the stabilization of ice II due to its lower zero-point energy when compared to that one of ices Ih, III, and V.Comment: 13 pages, 8 figures, 5 table

Can new generations explain neutrino masses?

In this talk we explore the possibility that the smallness of the observed neutrino masses is naturally understood in a modified version of the standard model with N extra generations of fermions and N right-handed neutrinos, in which light neutrino masses are generated at two loops. We find that with N = 1 it is not possible to fit the observed spectrum of masses and mixings while with N = 2 it is. Within this extension, we analyse the parameters which are allowed and the possible phenomenological signals of the model in future experiments. Contribution to the proceedings of Les Rencontres de Moriond EW 2011, Young Scientist Forum

Spectroscopic and physical parameters of Galactic O-type stars. II. Observational constraints on projected rotational and extra broadening velocities as a function of fundamental parameters and stellar evolution

Rotation is of key importance for the evolution of hot massive stars, however, the rotational velocities of these stars are difficult to determine. Based on our own data for 31 Galactic O stars and incorporating similar data for 86 OB supergiants from the literature, we aim at investigating the properties of rotational and extra line-broadening as a function of stellar parameters and at testing model predictions about the evolution of stellar rotation. Fundamental stellar parameters were determined by means of the code FASTWIND. Projected rotational and extra broadening velocities originate from a combined Ft + GOF method. Model calculations published previously were used to estimate the initial evolutionary masses. The sample O stars with Minit > 50 Msun rotate with less that 26% of their break-up velocity, and they also lack objects with v sin i 35 Msun on the hotter side of the bi-stability jump, the observed and predicted rotational rates agree quite well; for those on the cooler side of the jump, the measured velocities are systematically higher than the predicted ones. In general, the derived extra broadening velocities decrease toward cooler Teff, whilst for later evolutionary phases they appear, at the same v sin i, higher for high-mass stars than for low-mass ones. None of the sample stars shows extra broadening velocities higher than 110 km/s. For the majority of the more massive stars, extra broadening either dominates or is in strong competition with rotation. Conclusions: For OB stars of solar metallicity, extra broadening is important and has to be accounted for in the analysis. When appearing at or close to the zero-age main sequence, most of the single and more massive stars rotate slower than previously thought. Model predictions for the evolution of rotation in hot massive stars may need to be updated.Comment: 15 pages, 10 figures, accepted for publication in A &

Rare-gas solids under pressure: A path-integral Monte Carlo simulation

Rare-gas solids (Ne, Ar, Kr, and Xe) under hydrostatic pressure up to 30 kbar have been studied by path-integral Monte Carlo simulations in the isothermal-isobaric ensemble. Results of these simulations have been compared with available experimental data and with those obtained from a quasiharmonic approximation (QHA). This comparison allows us to quantify the overall anharmonicity of the lattice vibrations and its influence on several structural and thermodynamic properties of rare-gas solids. The vibrational energy increases with pressure, but this increase is slower than that of the elastic energy, which dominates at high pressures. In the PIMC simulations, the vibrational kinetic energy is found to be larger than the corresponding potential energy, and the relative difference between both energies decreases as the applied pressure is raised. The accuracy of the QHA increases for rising pressure.Comment: 9 pages, 6 figure

Infrared 3D Observations of Nearby Active Galaxies

We present multi-wavelength imaging observations of three nearby and famous active galaxies obtained with NICMOS, ISOCAM and the MPE near-IR integral field spectrometer. The data reveal a variety of features and properties that are missed in optical studies and in traditional IR monodimensional spectroscopy.Comment: 6 pages, to appear in "Imaging the Universe in Three Dimensions: Astrophysics with Advanced Multi-Wavelength Imaging Devices", eds. W. van Breugel and J. Bland-Hawthorn, needs pasp3D.st

Profit efficiency among Kenyan smallholders milk producers: A case study of Meru-South district, Kenya

Production inefficiency is usually analyzed by economical efficiency, which is composed of two components-technical and allocative efficiencies. This study provided a direct measure of production efficiency of the smallholder milk producers in Kenya using a stochastic profit frontier and inefficiency model. The primary data were collected, using IMPACT (intergrated modeling platform for mixed animal crops systems) structured questionnaire and includes four conventional inputs and socio-economic factors affecting production. The result showed that profit efficiencies of the sampled farmers varied widely between 26% and 73% with a mean of 60% suggesting that an estimated 40% of the profit is lost due to a combination of both technical and allocative inefficiencies in the smallholder dairy milk production. This study further observed that level of education, experience, and the size of the farm influenced profit efficiency positively while profit efficiency decreased with age. This implies that profit inefficiency among smallholder dairy milk producers can be reduced significantly with improvement in the level of education of sampled farmer